Difference Between Homopolymer and Copolymer

Main Difference – Homopolymer vs Copolymer

Polymers are the macromolecules formed by linking of a large number of small units called monomers through chemical reactions. The process of formation of polymers is called polymerization. The chemical and physical properties of a polymer mainly depend on the type of monomer or monomers used to form the polymer. Based on the number of different types of monomers used to form a polymer molecule, there are two types of polymers: homopolymers and copolymers. The main difference between homopolymer and copolymer is that homopolymers are produced by using a single type of monomer, whereas copolymers are formed by using two different types of monomers. Because of this difference, both homopolymers and copolymers gain their unique set of properties.

This article explores,

1. What is a Homopolymer?
        – Definition, Formation, Structure and Characteristics

2. What is a Copolymer?
        – Definition, Formation, Structure and Characteristics

3. What is the difference between Homopolymer and Copolymer?
Difference Between Homopolymer and Copolymer - Comparison Summary

What is a Homopolymer

A homopolymer is formed by a single type of monomer. Thus, it consists of only one type of repeating unit. homopolymers are usually made by a polymerization technique called addition polymerization. Monomers that undergo this process must have either double or single bonds. The repeating unit enclosed in brackets represents the chemical structure of a homopolymer. For example, if we take ‘X’ as the repeating unit of a particular homopolymer, we can represent the structure of that homopolymer as –[X]-n. Usually, when naming the homopolymers, the word ‘poly’ is used as the prefix in most cases, followed by the chemical name of the repeating unit. For example, repeating unit ‘vinyl chloride’ forms a polymer called polyvinyl chloride (PVC). Some common examples of homopolymers include polyethylene, polypropylene, polystyrene, polytetrafluoroethylene, and poly(methyl methacrylate).

Main Difference - Homopolymer vs Copolymer

What is a Copolymer

A polymer formed from more than one type of monomer is called a copolymer. Thus, it contains two or more different types of repeating units. Usually, most of the copolymers are formed through a process called condensation polymerization. There are several classes of copolymers: block copolymers, alternating copolymers, graft copolymers, and statistical copolymers. The structure of these classes can be explained simply by using two types of hypothetical repeating units namely; A and B. In statistical copolymers, the sequence of repeating units obeys known statistical laws. Random copolymers are an example for statistical copolymers that have a random distribution of repeat units (ex: ̴ ̴ A-B-B-A-A-A-A-B-B-B-A-B-B ̴ ̴). Alternating copolymers consist of only two types of repeat units, which are arranged alternative along the polymer chain (Ex: ̴ ̴ A-B-A-B-A-B-A-B-A- B ̴ ̴). In block copolymers, the repeat units exist in blocks of the same type (ex: ̴ ̴ A-A-A-A-A-B-B-B-B-B ̴ ̴). Block copolymers are linear copolymers. Graft copolymers contain branches of different chemical structures attached to main chain. Some common copolymers include poly(vinyl acetate), poly (ethylene oxide), poly(ethylene terephthalate) and poly(hexamethylene sebaacamide).

Structure of the condensation polymerization between Formaldehyde and Phenole to Bakelite 

Structure of the condensation polymerization between Formaldehyde and Phenole to Bakelite

Difference Between Homopolymer and Copolymer

Definition

Homopolymers consist of single species of repeating units.

Copolymers consist of two or more type of repeating units.

Amount of Monomer Species

Homopolymers have a single type of monomer.

Copolymers have two or more types of monomers.

Chemical Structure

Homopolymers usually have a simple structure.

Copolymers have a complex structure.

Polymerization Process

Homopolymers are formed through addition polymerization.

Copolymers are formed through condensation polymerization.

Examples

Homopolymers include PVC, polyethylene, polypropylene, polystyrene, polytetrafluoroethylene, and poly(methyl methacrylate).

Copolymers include poly (vinyl acetate), poly (ethylene oxide), poly(ethylene terephthalate) and poly(hexamethylene sebaacamide).

References:

Carraher, C. E. (2012). Introduction to Polymer Chemistry (3rd ed.). CRC Press.
Gedde, U. (1995). Polymer Physics. Springer Science & Business Media.
Young, R. J., & Lowell, P. A. (2011). Introduction to Polymers. CRC Press.
 
 
Image Courtesy:

“Polymerisation of Ethylene” – derived by Polymérisation de l’éthylène By Cjp24 – Own work (Public Domain) via

“Polykondensation Bakelit 1.” By MaChe (talk) – Own work (Public Domain) via

About the Author: Yashoda

Yashoda has been a freelance writer in the field of biology for about four years. He is an expert in conducting research related to polymer chemistry and nano-technology. He holds a B.Sc. (Hons) degree in Applied Science and a Master of Science degree in Industrial Chemistry.


Related pages


example of polar and nonpolar moleculeshimalayan rivers and peninsular riversparatyphoid symptomsdifference between bite and bytereactance of a circuitwhat is the difference between mitochondrial dna and nuclear dnadoes sherbet contain lactosefunction microvilliboxer dog behaviourrelation between yield strength and tensile strengthadjective and noun clauseswhat is enjabmentwhat is figurative meaning and literal meaningcolloid and suspensionsimilarities between cellulose and starchnucleotide and nucleosidemeaning of avengingunit of absolute permittivitydefine hydrogen bondingwhat is the difference between bipolar and bpdsemantic vs syntacticdefinition of consonants and vowelsdifference between aldehyde and ketoneis absorbance directly proportional to concentrationwhat is the difference between pronounce and enunciateperoxisomes and lysosomesbullmastiff characteristicswhat is the difference between king and emperorexamples of exclamation markswhat is the difference between a phenotype and genotypeexample of indefinite pronounround and flat character definitionrelationship between phonetics and phonologywhat is the difference between a whale and a sharkc3 photosynthesis definitionexample sentences of onomatopoeiaprove verbdepth micrometer readingreciprocating pump usesdifference between countable and uncountable nounsdifference between uvula and epiglottisflying ants vs termites differencewhat is the difference between a panther and a jaguarpokemon cards symbolsdifference between phd and professional doctoratedefinition of regular polygonsgst refund sydneystructure for ethyl alcoholmelting point defdifference between fish and whaledifference between crocodile and alligatorwhat is horatian satirespherical symmetry biologywhat is herbivores carnivores and omnivoresphysical properties alkanesnail polish vs nail lacquerpsychoanalytical criticismwhat is the difference between a cpap and bipapcharacters in melodramaprokaryotic vs eukaryotic chartexamples of normative economicsdefine bakerydistinguish between hypertonic hypotonic and isotonic solutionsmastiff bullmastiffnonpolar bonds examplesgenetic recombination crossing overthe difference between sorbet and sherbetexamples of tyndall effectunit product cost calculatordescribe the differences between mitosis and meiosisstructural formula of maltosediffusivity definitiongnostic theistprophase in meiosiswhat is the difference between a hog and a pigexample of interrogative adjectiveare shark mammals